March 2024
Publication: Science of The Total Environment
Author(s): M. Dumont, Z. Etheridge, R.W. McDowell
Nitrate‑nitrogen (NO3-N) is a contaminant of concern in groundwater worldwide. Stakeholders need information on the ability to detect changes in NO3-N concentrations to prove that land management practices are meeting water quality aims.
We created a database of quarterly to monthly NO3-N measurements in 948 sites across New Zealand; 186 of those sites had mean residence time (MRT) data.
New Zealand has set a target of sufficient land use mitigations in the next 30 years to ensure steady state surface water concentrations do not exceed 2.4 mg L−1.
Here we assess whether the current monitoring network could identify the impacts of these mitigations, assuming that the mitigations are successfully implemented at the source.
Only 41% of the network could detect statistically significant reductions with the current standard quarterly sampling after 30 years of monitoring. The percentage of sites increased to 60% with increased monitoring frequency (often weekly) but this required a 100–300% increase in monitoring costs.
However, policy makers and stakeholders typically require information on policy and mitigation effectiveness within 5–10 years. Detection within 5–10 years was very unlikely (0–20% of sites) regardless of the sampling frequency.
Importantly, these analyses include the impacts of groundwater lag and temporal dispersion on the likelihood of detecting change, ignoring these impacts, incorrectly, yields a much higher likelihood of detecting reductions.
We conclude that the current monitoring network is unlikely to be fit for the purpose of detecting NO3-N reductions within practical timeframes or budgets.
Furthermore, we conclude that lag and temporal dispersion effects must be included in detection power calculations; we therefore recommend that MRT data is regularly collected. We also provide a python packsage to enable easy detection power calculations with lag and temporal dispersion impacts, thereby supporting the development of robust change-detection monitoring networks